η6-Fluorene and η5-fluorenyl complexes of iron and manganese; X-ray structure of (η5-cyclopentadienyl)(η6-fluorenyl)iron
- 1 January 1976
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 688-689
- https://doi.org/10.1039/c39760000688
Abstract
Reversible deprotonation of [Fe(C5H5)(η6-fluorene)]PF6 and [Mn(η6-fluorene)(CO)3]PF6 initially produces zwitterionic complexes wherein co-ordination to the six-membered ring is retained, and the manganese complex very slowly reverts to the isomeric η5 complex, [Mn(η5-fluorenyl)(CO)3]; the X-ray structure of the iron compound [Fe(C5H5)(C13H9)] has been determined.Keywords
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