Structural evidence for the participation of P–X σ* orbitals in metal–PX3bonding
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1310-1311
- https://doi.org/10.1039/c39850001310
Abstract
Examination of metal–phosphorus and phosphorus–substituent atom bond length in a series of reduction–oxidation related pairs of transition metal phosphine complexes yields evidence of the participation of P–substitution σ* orbitals in the π-acceptor function of the phosphine.Keywords
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