Synthesis, Spectroscopic Characterization, and Reactivity of the Unusual Five-Coordinate Hydrido−Vinylidene Complex OsHCl(CCHPh)(PiPr3)2: Precursor for Dioxygen Activation
- 1 February 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 16 (4) , 636-645
- https://doi.org/10.1021/om960525t
Abstract
No abstract availableKeywords
This publication has 69 references indexed in Scilit:
- Synthesis, reactivity and catalytic activity of [RuH(η1-OCMe2)(CO)2(PPri3)2]BF4J. Chem. Soc., Dalton Trans., 1995
- Reactions of RuHCl(CO)(PiPr3)2 with Alkyn-1-ols: Synthesis of Ruthenium(II) Hydroxyvinyl and Vinylcarbene ComplexesOrganometallics, 1994
- Synthesis of Polymerizable Carbene and Alkenyl Ruthenium Complexes and of a Ruthenium Containing CopolymerOrganometallics, 1994
- Reactions of Osmium Hydride Complexes with Terminal Alkynes: Synthesis and Catalytic Activity of OsH(.eta.2-O2CCH3)(C:CHPh)(PiPr3)2Organometallics, 1994
- Modulation of reactivity and stereochemistry of substrate binding by the group X in RuHX(CO)(P-tert-Bu2Me)2Inorganic Chemistry, 1993
- Synthesis of new hydride-carbyne and hydride-vinylcarbyne complexes of osmium(II) by reaction of OsH2Cl2(P-iso-Pr3)2 with terminal alkynesJournal of the American Chemical Society, 1993
- Vinylidene transition-metal complexes. XIX. Preparation of vinylideneruthenium complexes promoted by hemilabile chelating phosphine ligandsOrganometallics, 1992
- Insertion reaction of acetone-d6 into the osmium-hydrogen bond of [OsHCl(CO)(P-iso-Pr3)2]: experimental evidence for the hydrogen-transfer mechanism from alcohols to ketonesInorganic Chemistry, 1991
- Coordination of H2 and O2 to [OsHCl(CO)(PiPr3)2]: A Catalytically Active M(η2‐H2) ComplexAngewandte Chemie International Edition in English, 1988
- On the mechanism of carbon-carbon bond formation in the CO hydrogenation reactionJournal of Catalysis, 1983