N-Boc-l-Valine-Connected Amidomonophosphane Rhodium(I) Catalyst for Asymmetric Arylation of N-Tosylarylimines with Arylboroxines
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- 15 June 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (26) , 8128-8129
- https://doi.org/10.1021/ja0475398
Abstract
A catalytic asymmetric arylation of sterically tuned imines with arylboroxines was developed by using N-Boc-l-valine-connected amidomonophosphane rhodium(I) catalyst in n-PrOH. The TMS group used for the steric tuning of imines is convertible to other functionalities that are applicable as a key foothold for the carbon−carbon bond-forming coupling reactions.Keywords
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