Platinum complex-catalysed polycondensation of tetrakis(dimethylsilyl)benzene with diynes. Synthesis of thermally stable and conducting polymers

Abstract
Dehydrogenative double silylation polymerisation of diynes with 1,2,4,5- tetrakis(dimethylsilyl) benzene in the presence of a catalytic amount of (ethylene)bis(triphenylphosphine)platinum gives new silicon-based polymers, which show high thermal stability and conductivity upon doping.

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