Metal–β-diketone complexes. Part II. Carbon-bonded platinum(II) complexes of trifluoroacetylacetone and benzoylacetone
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1453-1456
- https://doi.org/10.1039/j19660001453
Abstract
The complexes K[Pt(diketone)2X](diketone = trifluoroacetylacetone and benzoylacetone, X = Cl or Br) have been prepared. The n.m.r. spectra of the trifluoroacetylacetone complexes and the infrared spectra of all the compounds indicate the presence of both oxygen- and carbon-bonded β-diketone groups. The factors which influence carbon as opposed to oxygen-bonding of β-diketones to metals are discussed.Keywords
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