Convenient Synthesis of Hetero Decalins
- 1 October 1996
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 26 (19) , 3527-3533
- https://doi.org/10.1080/00397919608003761
Abstract
A novel synthesis of heterodecalins has been achieved through Baylis-Hillman reaction of 2-formyl-4,4-dimethylcyclohexa-2,5-dien-1-one (1) with unsaturated vinyl systems, followed by allylic migration of hydroxyl group and cyclization or benzyl amine addition to yield the oxa- and aza- decalins respectively.Keywords
This publication has 11 references indexed in Scilit:
- Microwave Mediated Extensive Rate Enhancement of the Baylis-Hillman ReactionSynlett, 1994
- Convenient synthesis of decalin systems of bioactive terpenoidsTetrahedron, 1993
- Unprecedented tandem Michael-ene reaction of 2-formylcyclohexa-2,5-dienone and subsequent unusual autoxidationThe Journal of Organic Chemistry, 1992
- A Convenient Synthesis of 3-Substituted-5, 5-dimethyl-tetrahydro-2-benzopyran-8-ones Through Hetero-Diels-Alder ReactionSynthetic Communications, 1992
- Tetracyclic Triterpenoids and Their Derivatives from Azadirachta indicaJournal of Natural Products, 1988
- Terpenoid antifeedants (Part II): The synthesis of drimane and clerodane insect antifeedantsRecueil des Travaux Chimiques des Pays-Bas, 1987
- A simple method for the efficient synthesis of unsaturated .beta.-dicarbonyl compoundsThe Journal of Organic Chemistry, 1981
- Diels-Alder reactions involving cross-conjugated dienones. Effects of substitution on reactivityJournal of the American Chemical Society, 1981
- Some metabolites of the marine sponges Smenospongia aurea and Smenospongia (.ident.Polyfibrospongia) echinaThe Journal of Organic Chemistry, 1980
- Stereoselective total syntheses of the fungitoxic hydroquinones (.+-.)-zonarol and (.+-.)-isozonarolThe Journal of Organic Chemistry, 1978