Bis(diazadiene)iron complexes, (R1MCR2–CR2NR1)2Fe1
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 24-25
- https://doi.org/10.1039/c39770000024
Abstract
Under reducing conditions diazadienes, R1NCR2 CR2–NR1(L), and iron salts give stable, tetracoordinate complexes L2Fe0; activation with organoaluminium compounds yields active homogeneous catalysts for highly selective 1,3-diene dimerisation and L2Fe adds 1 mol of CO reversibly, excess of CO giving LFe(CO)3.Keywords
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