Staircase-form assembly with 5,15-bis(imidazol-4-yl)porphinatogallium steps
- 6 March 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 27 (4) , 743-747
- https://doi.org/10.1039/b211839d
Abstract
Large supramolecular assemblies of 5,15-bis(imidazol-4-yl)porphinatogallium 2Ga have been synthesized by hexacoordination of two imidazolyl groups to Ga(III) in a staircase arrangement of porphyrin planes as each “step”. The structure of the supramolecular assembly was characterized by UV, X-ray diffraction, and AFM. The conductivity of 2Ga films was enhanced 8 times by photoirradiation.Keywords
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