The far infrared spectrum of 14N16O2

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Abstract
High resolution Fourier transform spectra in the 8–200 cm-1 spectral region have been used to analyse the pure rotation spectrum of nitrogen dioxide. In this way, the spin rotation levels of the (000) state were accurately measured for Ka up to 14 and N up to 54. Using a hamiltonian which takes the spin-rotation and the hyperfine operators explicitly into account, it has been possible to derive a complete set of molecular parameters (rotational, spin-rotation and hyperfine constants) for the (000) state of 14N16O2 from these experimental data and from the available microwave measurements. Numerous perturbations due to the hyperfine Fermi contact operator were analysed as well as a local resonance [42 0 42, J = 41·5] ↔ [41 2 40, J = 41·5] due to the electron spin-rotation interaction. Finally, a synthetic spectrum of the (000) ← (000) band of 14N16O2 including all hyperfine transitions has been computed, covering the 0–235 cm-1 spectral region.