One Pot Synthesis of Haloacetylenes from Trimethylsilylacetylenes
- 1 January 1994
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1994 (07) , 485-486
- https://doi.org/10.1055/s-1994-22897
Abstract
An efficient and convenient method for one step conversion of trimethylsilylacetylenes into haloacetylenes has been developed. This method is sufficiently mild to apply a variety of substrates having many kinds of functional group. The validity of this method is demonstrated in the synthesis of simple model compound of esperamicin/calicheamicin aglycon.Keywords
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