Allylmetalation of 1-silylalkynes by 2-bromozincmethyl-2-propenyl ethers followed by pd(0)-catalyzed cyclization: A one-pot synthesis of 4-methylenecyclopentenes
- 31 December 1987
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 28 (25) , 2889-2892
- https://doi.org/10.1016/s0040-4039(00)96236-1
Abstract
No abstract availableKeywords
This publication has 18 references indexed in Scilit:
- Enantioselective Synthesis of β‐Necrodol and of 1‐Epi‐β‐necrodol via Asymmetric 1,4‐Addition and Magnesium‐Ene Cyclization. Preliminary CommunicationHelvetica Chimica Acta, 1986
- The origin of the configurational instability of 1-silyl-1-alkenyllithiums and related alkenylmetalsJournal of the American Chemical Society, 1986
- Fünfgliedrige Ringe durch [3+2]‐Cycloaddition mit Trimethylenmethan und SyntheseäquivalentenAngewandte Chemie, 1986
- Metal-promoted cyclization: VI. Palladium-catalyzed cyclization via intramolecular allylation of alkenylmetalsJournal of Organometallic Chemistry, 1985
- 4‐Methylen‐1‐cyclopentene aus Methylencyclopropanen und Alkinyl‐trimethylsilanenAngewandte Chemie, 1985
- Addition of allylic Grignard reagents to homoallylic alcohols: structural effects on addition and cyclizationOrganometallics, 1984
- Carbometallation: addition of organometallic compounds to isolated multiple bonds in functionally substituted compoundsJournal of Organometallic Chemistry, 1983
- Allylmetalations. The allylzincation of 1-(trimethylsilyl)-1-alkynesThe Journal of Organic Chemistry, 1983
- Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynesJournal of the American Chemical Society, 1983
- Carbometallation (C-Metallation) of Alkynes: Stereospecific Synthesis of Alkenyl DerivativesSynthesis, 1981