Excess Volumes of Binary Mixtures of Alcohols in Methylcyclohexane
- 1 March 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (5) , 788-790
- https://doi.org/10.1139/v74-123
Abstract
Excess volumes of binary mixtures of alcohols in methylcyclohexane have been determined at 30.0 and 40.0 °C, using a modified dilatometer of Brown and Smith. The systems include: (I) 1-propanol – methylcyclohexane, (2) 1-butanol – methylcyclohexane, (3) 1-pentanol–methylcyclohexane, and (4) 1-hexanol–methylcyclohexane. The VE values are found to be positive over the entire range of composition in all the four systems and the values are interpreted on the basis of the structure-breaking effect of methylcyclohexane.Keywords
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