Spectro-electrochemical methods in the study of short-lived intermediates
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Faraday Discussions of the Chemical Society
- Vol. 56, 16-27
- https://doi.org/10.1039/dc9735600016
Abstract
The theoretical and experimental state of the art of spectro-electrochemistry as directed toward the study of short-lived intermediates is discussed. Particular emphasis is placed on the detection, characterization and kinetic monitoring of reactive intermediates during potential pulse and relaxation periods. Nucleophilic addition to radical dations with digital simulation of the possible mechanisms for the pulse-relaxation are presented using the thianthrene system as a working model.Keywords
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