THE SYNTHESIS AND STRUCTURE OF THE FIRST REPRESENTATIVES OF OLIGOARYLENEPHOSPHOCYCLANES
- 1 May 1995
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 102 (1-4) , 143-154
- https://doi.org/10.1080/10426509508042552
Abstract
Based on phenylphosphonous acid tetraethyldiamide and 2,2-di(p-oxyphenyl)propane diarylenecyclo-phenylphosphonite is synthesized. Its oxidation and sulfurization is investigated. It is shown that these reactions are stereospecific and lead to cis-isomers. The compounds obtained are the first representatives of oligoarylenephosphocyclanes. The structure of these compounds is confirmed by an X-ray structure analysis.Keywords
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