Polymeric anionic networks using dibromine as a crosslinker; the preparation and crystal structure of [(C4H9)4N]2[Pt2Br10]·(Br2)7and [(C4H9)4N]2[PtBr4Cl2]·(Br2)6
- 21 August 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 2180-2181
- https://doi.org/10.1039/b205712n
Abstract
The reaction of M[PtX3(CO)] (M+ = [(C4H9)4N]+, X = Br, Cl) with an excess of Br2 gives the new platinum(IV) salts, [(C4H9)4N]2[Pt2Br10]·(Br2)7, 1, and [(C4H9)4N]2[PtBr4Cl2]·(Br2)6, 2, which, in the solid state, contain strong Br Br interactions resulting in the formation of polymeric networks; they could provide useful solid storage reservoirs for elemental bromine.Keywords
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