A Homogeneous Platinum Catalyst in the Stationary BF3 · H2O Phase for the Hydrogenation of Arenes
- 1 August 1991
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 30 (8) , 1009-1011
- https://doi.org/10.1002/anie.199110091
Abstract
The advantages of homogeneous and heterogeneous catalytic systems are combined in stationary liquid‐phase catalysts such as the system [PtCl2,(CH3CN)2] in BF3 · H2O on clay or silica supports, which is used here for hydrogenation of arenes. The hydrogenation can be performed under relatively mild conditions, the products are separable by simple filtration, and the hydrogenation proceeds selectively, as shown for a 1 : 1 : 1 : 1 mixture of benzene, toluene, o‐xylene, and 1,2,4‐trimethylbenzene.Keywords
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