Polymer-Induced Repulsive Forces: Exponential Scaling
- 23 February 1998
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 80 (8) , 1778-1781
- https://doi.org/10.1103/physrevlett.80.1778
Abstract
The polymer-induced repulsive interactions between the surfaces of a liquid film are measured for two systems using two force measurement techniques, in the case where the polymer is in a good solvent and adsorbs at the liquid surface. The force decays exponentially with the film thickness with a decay length proportional to the radius of gyration. The data are compared with a recent theoretical work which predicts a repulsive exponentially decaying force at large thicknesses.Keywords
This publication has 10 references indexed in Scilit:
- Interaction between Two Adsorbing Plates: The Effect of Polymer Chain EndsMacromolecules, 1997
- Forces Between Emulsion Droplets: Role of Surface Charges and Excess SurfactantJournal de Physique II, 1996
- Adsorption of Polymer Solutions onto a Flat SurfaceMacromolecules, 1996
- Measurement of Forces Between Surfaces in Polymer FluidsAnnual Review of Physical Chemistry, 1989
- Forces between adsorbed PVA layersColloids and Surfaces, 1988
- Forces between two adsorbed polyethylene oxide layers immersed in a good aqueous solventNature, 1982
- Polymers at an interface. 2. Interaction between two plates carrying adsorbed polymer layersMacromolecules, 1982
- Polymer solutions near an interface. Adsorption and depletion layersMacromolecules, 1981
- Experimentelle Untersuchung der Sterischen Stabilisierung von Emulsionen durch PolyvinylalkoholColloid and Polymer Science, 1979
- Direct measurement of the variation of double-layer repulsion with distanceDiscussions of the Faraday Society, 1966