Silyl phosphites. Part 20. A facile synthesis of phosphoenolpyruvate and its analogue utilizing in situ generated trimethylsilyl bromide
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 11,p. 2509-2513
- https://doi.org/10.1039/p19820002509
Abstract
Phosphoenolpyruvate (PEP) has been synthesized from pyruvic acid and dimethyl trimethylsilyl phosphite in high yield by a new route which involves, successively, trimethylsilylation, bromination, and a Perkow reaction. A PEP analogue of 1-(dihydroxyphosphinyl)vinyl phosphate (1) has also been prepared.This publication has 3 references indexed in Scilit:
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