CHEMISTRY OF ORGANOSILICON COMPOUNDS CXVI. FLUORIDE ION-PROMOTED ISOMERIZATION OF METHYL-SUBSTITUTED ALLYLSILANES. REGIOSELECTIVE SYNTHESES OF ALLYLSILANES
- 5 August 1978
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 7 (8) , 901-904
- https://doi.org/10.1246/cl.1978.901
Abstract
Fluoride ion-catalyzed isomerization of methyl-substituted allylsilanes is reported. In the reaction, a regioisomer of allylsilanes, in which the silicon atom binds to the less substituted carbon atom of the allylic group, is obtained. Accordingly, the reaction is useful as a new route to regioselective synthesis of allylsilanes.This publication has 5 references indexed in Scilit:
- Stereochemistry of the regiospecific hydrosilylation of isoprene catalyzed by a phosphine-palladium complexJournal of Organometallic Chemistry, 1977
- Chemistry of organosilicon compounds. 99. Conjugate addition of allylsilanes to .alpha.,.beta.-enones. A New method of stereoselective introduction of the angular allyl group in fused cyclic .alpha.,.beta.-enonesJournal of the American Chemical Society, 1977
- The Reaction of the Butenyl Grignard Reagent with TrimethylchlorosilaneBulletin of the Chemical Society of Japan, 1976
- The preparation of organolithium reagents by the transmetalation reactionJournal of Organometallic Chemistry, 1974
- Kinetics, stereochemistry, and mechanisms of the silaalylic and silapropynylic rearrangementsJournal of the American Chemical Society, 1973