Synthesis of (2S,3S)-[3-2H1]-, (2S,3R)-[2,3-2H2]-, (2S,3S4RS)-[3-2H1,4-3H1]-, and (2S,3R,4RS)-[2,3-2H2,4-3H1]-glutamic acids
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1163-1165
- https://doi.org/10.1039/c39790001163
Abstract
Synthesis of (2S,3S)-[3-2H1]-, (2S,3R)-[2,3-2H2]-, (2S,3S,4RS)-[3-2H1,4-3H1]-, and (2S,3R,4RS)-[2,3-2H2,4-3H1]- glutamic acids in useful amounts has been achieved; the route involves a step where Wolff rearrangement occurs with retention of stereochemistry at a secondary chiral centre.Keywords
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