Multi-electron satellites in core electron photoemission from 3d0ions in solids
- 11 December 1973
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 6 (24) , L493-L495
- https://doi.org/10.1088/0022-3719/6/24/012
Abstract
'Shake-up' satellite peaks have been observed for 2s and 2p lines in the X-ray photoemission spectra of solid compounds of the d0 ions Sc3+ and Ti4+. For this configuration (and presumably for the other 3d ions) these satellites cannot arise from simultaneous transitions of electrons from 3d orbitals; the data suggest that they originate from the excitation of electrons in ligand orbitals to the metal 3d states.Keywords
This publication has 7 references indexed in Scilit:
- Large satellite separations in core electron photoemission lines from TiF3Journal of Physics C: Solid State Physics, 1973
- X-ray photoemission satellites; surface or bulk effect?Journal of Electron Spectroscopy and Related Phenomena, 1972
- Characterization of oxygen species adsorbed on copper and nickel oxides by X-ray photoelectron spectroscopySurface Science, 1972
- X-ray photoelectron spectroscopy of copper compoundsMolecular Physics, 1972
- Split photo-electron signals from the unique closed-shell cation lanthanum(III)Chemical Physics Letters, 1972
- Origins of Satellites on Inner-Shell Photoelectron SpectraPhysical Review Letters, 1971
- X-Ray Photoelectron Spectroscopy of Solids; Evidence of Band StructurePhysical Review B, 1971