The effect of spacer chain length on ion binding to bidentate α,ω-diamines: Contrasting ordering for H+and Li+ion affinities
- 26 January 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1420-1422
- https://doi.org/10.1039/b414426k
Abstract
Electrospray ionisation mass spectrometry studies and quantum chemical calculations indicate that bidentate ligation of Li+ ion to the diamines leads to symmetric bridging and exhibits contrasting relative affinity orderings compared to that of proton for α,ω-diamines.Keywords
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