Stereoselective Michael/aldol tandem reaction triggered by thiolate anion or analogues
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1095-1096
- https://doi.org/10.1039/a800870a
Abstract
A combination of a tert-butyl α,β-unsaturated ester, an aldehyde and lithium thiophenolate in CH2Cl2 undergoes a one-pot Michael/aldol tandem reaction to give a condensation adduct of the three components, an α-phenylthiomethyl-β-hydroxy ester, in good yield with high syn-selectivity.Keywords
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