Steric Effects. Internal-Rotation of 1-Aryl-8-Phenylnaphthalenes
- 1 January 1987
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 40 (6) , 1107-1126
- https://doi.org/10.1071/ch9871107
Abstract
A general, albeit low-yielding, synthesis of 1-aryl-8-phenylnaphthalenes was devised and used to prepare three l-(3'-X-5'-isopropylphenyl)-8-phenylnaphthalenes (X = H, F, Br). Activation parameters for the rotation of the 3'-X-5'4sopropylphenyl group were determined by dynamic m.m.r. spectroscopy.Keywords
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