Effects of Atomic Interactions on the Absorption and Emission of Radiation

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Abstract
The processes of absorption and emission of radiation by a system of two interacting atoms is investigated. Separation between the atoms is assumed to be much larger than the atomic diameter, and interactions considered are those between the individual atoms and the radiation field and the electrostatic interaction between the atoms. Calculations include those for the time‐dependent probability amplitude of the intermediate and final states as well as that of the emission line shape. The line shape of the emitted radiation consists of two peaks whose amplitude, separation, and half‐width are functions of both the internuclear separation R of the atoms and the energy difference of the excited states of the two atoms. For a large energy difference, the peaks are distinct; for small energy differences, the peaks are distinct at smaller separations, but merge toward the line shape characteristic of a single, isolated atom as R increases.

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