ASYMMETRIC REDUCTION OF PROCHIRAL KETONES WITH A CHIRAL REDUCING AGENT PREPARED FROM STANNOUS CHLORIDE, CHIRAL DIAMINE AS A LIGAND, AND DIISOBUTYLALUMINUM HYDRIDE
- 5 December 1984
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 13 (12) , 2071-2074
- https://doi.org/10.1246/cl.1984.2071
Abstract
A new chiral reducing agent, prepared by treatment of a mixture of stannous chloride and a chiral diamine derived from (S)-proline with diisobutylaluminum hydride, is effective for asymmetric reduction of prochiral ketones.Keywords
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