Diels–Alder reactions involving cis-1,2-isopropylidenedioxycyclohexa-3,5-diene and enzymatic resolution of one of the adducts
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1628-1629
- https://doi.org/10.1039/c39880001628
Abstract
cis-1,2-Isopropylidenedioxycyclohexa-3,5-diene undergoes Diels–Alder [4 + 2] cycloaddition reactions with a variety of dienophiles including dimethyl acetylenedicarboxylate; the adduct formed with the latter dienophile was hydrolysed stereoselectively by pig liver esterase.Keywords
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