Stereo-controlled synthesis of (–)-ajmalicine and (–)-tetrahydroalstonine

Abstract
Stereo-controlled synthesis of the heteroyohimbine alkaloids, (–)-ajmalicine and (–)-tetrahydroalstonine, has been developed starting from diethyl L-tartrate by employing the intramolecular hetero-Diels–Alder reaction as the key step.

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