Low-Frequency Fundamentals of Some Metal Carbonyls
- 15 June 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 36 (12) , 3321-3324
- https://doi.org/10.1063/1.1732463
Abstract
The carbon‐metal‐carbon bending fundamentals of several metal carbonyls have been determined by the analysis of their combinations with the carbonyl stretching frequencies near 5 μ and by direct observation in the far infrared (60–120 cm—1). The following vapor‐phase frequencies were obtained (in cm—1): Fe(CO)5: 104 (A2″), 114 and ∼68 (E′), 95 (E″); Ni(CO)4: 74 (F2), 68 (E); Cr(CO)6: 98 (F1u), 90 (F2g); Mo(CO)6: 81 (F1u), 81 (F2g); W(CO)6: 81 (F1u), 83 (F2g).Keywords
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