Radical cations and anions of s-tetrazines: an electron spin resonance study
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 837-838
- https://doi.org/10.1039/c39860000837
Abstract
Liquid- and solid-state studies of the radical cations and anions of s-tetrazine and various derivatives thereof show that the anions have a π-SOMO concentrated on the four ring nitrogen atoms whilst all but the (–NMe2)2 derivative form σ-cations, again with the SOMO confined to the four nitrogen atoms.Keywords
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