X-Ray structural analysis of a tetra-manganess(II) complex of a new (4 × 4) Schiff-base macrocycle incorporating a cubane-like Mn4(alkoxy)4core
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 158-159
- https://doi.org/10.1039/c39850000158
Abstract
X-Ray structure analysis of the tetranuclear Schiff-base macrocylic complex [C12H14N3OMnII]4(ClO4)4 shows the (4 × 4) macrocycle is folded so that the four alkoxide oxygen atoms cap the faces of a tetrahedral Mn4 cluster, resulting in a cubane-type stereochemistry.Keywords
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