1,3-Organometallic insertion reactions with trimethylsilyldiazomethane: synthesis of (trimethylsilyl)methylazo–transition metal complexes
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1061-1062
- https://doi.org/10.1039/c29690001061
Abstract
The reaction between π-C5H5(OC)3M–H (M = Mo or W) and Me3SiCHN2 provides the first example of a 1,3-organometallic insertion and the products π-C5H5(OC)2M·NN·CH2SiMe3 are the first stable alkylazo-compounds.Keywords
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