DIRECT SPECTROPHOTOMETRIC METHOD FOR THE DETERMINATION OF ALKYLBENZENESULFONATE WITH 1-(4-N-METHYLPYRIDINIUMAZO)-4-(4-AMINOPHENYLAZO) NAPHTHALENE IODIDE

Abstract
A new reagent, 1-(4-N-methylpyridiniumazo)-4-(4-aminophenylazo) naphthalene iodide, can react with sodium alkylbenzenesulfonate to show a color change in an aqueous medium. The calibration graph is straight line over the range from 8×10−6 to 3.0×10−5 M of sodium dodecylbenzenesulfonate. The practical molar absorptivity is 1.8×104 1 mol−1 cm−1 at 594 nm.