Lösungsstrukturen eines Paares stabiler Hexaamincobalt(III/II)‐Konformere
- 15 September 1997
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 109 (18) , 2089-2090
- https://doi.org/10.1002/ange.19971091823
Abstract
Die Struktur der erstaunlichen blauen Form einer neuen Hexaamincobalt(III)‐Käfigverbindung (Lewis‐Formel rechts) war nicht bekannt, die des gelben Konformers dagegen bereits experimentell bestimmt. Mit einer Kombination aus Kraftfeldrechnungen und der Simulation von spektroskopischen und elektrochemischen Eigenschaften können die Struktur bestimmt und das beispiellos schwache Ligandenfeld und das hohe Redoxpotential interpretiert werden. magnified imageKeywords
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