Dinitrogen, hydrido-, and carbonyl complexes of tungsten
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 22,p. 2492-2496
- https://doi.org/10.1039/dt9720002492
Abstract
The reduction of trans-[WCl4(PR3)2](PR3= tertiary phosphine) by sodium amalgam in tetrahydrofuran solution at ca. 20° under argon, dinitrogen, dihydrogen or carbon monoxide is discussed. The syntheses of hydrido-, dinitrogen, and carbonyl complexes are achieved by these routes. The interconversions and isomerisations of pentacarbonyl-, tetracarbonyl-, and tricarbonyl-tungsten complexes containing tertiary phosphines are described.Keywords
This publication has 0 references indexed in Scilit: