Classical radiation spectra of long-lived H+ 3-complexes
- 10 April 1988
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 63 (5) , 779-790
- https://doi.org/10.1080/00268978800100561
Abstract
Spectral analysis was performed of classical trajectories simulating collisions of H+ with H2 which form long-lived complexes. The dipole moment μ(t) and several geometrical variables are analysed, and their spectra shown and interpreted in terms of known dynamical features of the motion. Correspondence with Einstein's A- and B-coefficients is used to derive estimates for the rates of the spontaneous and induced (laser-assisted) radiative association reaction H+ + H2 → H+ 3 + hv.Keywords
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