Enhanced Raman scattering by fractal clusters: Scale-invariant theory
- 1 August 1992
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 46 (5) , 2821-2830
- https://doi.org/10.1103/physrevb.46.2821
Abstract
A scale-invariant theory of Raman scattering of light by fractal clusters is developed. The enhancement factor of Raman scattering is shown to scale in terms of a properly chosen spectral variable X. The critical indices of the enhancement factor are found to be determined by the optical spectral dimension of the fractal. Numerical modeling is carried out and shown to support the analytical results obtained. The theory, which does not contain any adjustable parameters, agrees well with experimental data on surface-enhanced Raman scattering over a wide spectral range.
This publication has 18 references indexed in Scilit:
- Fractals: optical susceptibility and giant raman scatteringThe European Physical Journal D, 1988
- The effects of random bond breaking on diffusion limited cluster–cluster aggregationThe Journal of Chemical Physics, 1985
- Surface-enhanced spectroscopyReviews of Modern Physics, 1985
- Local fields in cavity sites of rough dielectric surfacesChemical Physics Letters, 1984
- Fractal Structures Formed by Kinetic Aggregation of Aqueous Gold ColloidsPhysical Review Letters, 1984
- Formation of Fractal Clusters and Networks by Irreversible Diffusion-Limited AggregationPhysical Review Letters, 1983
- Scaling of Kinetically Growing ClustersPhysical Review Letters, 1983
- Lightning rod effect in surface enhanced Raman scatteringThe Journal of Chemical Physics, 1982
- Giant Raman scattering of light by molecules adsorbed on the surface of a metalSoviet Physics Uspekhi, 1981
- The interaction between electromagnetic resonances and its role in spectroscopic studies of molecules adsorbed on colloidal particles or metal spheresSurface Science, 1981