Cyanomanganese-(I) and -(II) carbonyls as redox-active donor ligands: the synthesis of novel paramagnetic heterobinuclear complexes
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 597-599
- https://doi.org/10.1039/c39900000597
Abstract
The cyanomanganese complexes trans-[Mn(CN)(CO)(dppm)2]z(z= 0, 1+)(dppm = Ph2PCH2PPh2), cis-[Mn(CN)(CO)2L(L–L)], and trans-[Mn(CN)(CO)2L(L–L)]z(z= 0, 1+) have been used as ligands in the synthesis of redox-active heterobinuclear complexes such as [L(L–L)(CO)2Mn(µ-CN)Ru(CO)2(PPh3)(o-O2C6Cl4)]z(z= 0, 1+) and [(dppm)2(CO)Mn(µ-CN)RhCl(CO)2]z(z= 0, 1+).Keywords
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