Hydrogen Bonding on the Surface of Poly(2-methoxyethyl acrylate)
- 10 September 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (39) , 12198-12199
- https://doi.org/10.1021/ja046183x
Abstract
Hydrogen bonding on the interface and in the bulk of a poly(2-methoxyethyl acrylate) (PMEA) thin film has been investigated by sum frequency generation, infrared reflection absorption, and Raman scattering measurements in different kinds of solutions containing hydrogen-bonding donators. These results indicate that the majority of the carbonyl groups on the PMEA surface are hydrogen-bonded with water or ethanol molecules, while the PMEA bulk is still dominated by the free carbonyl group.Keywords
This publication has 11 references indexed in Scilit:
- Effect of glass transition temperature (Tg) on the absorption of bisphenol A in poly(acrylate)s thin filmsVibrational Spectroscopy, 2004
- Organization of Water Layers at Hydrophilic InterfacesChemphyschem, 2003
- Bridged and Open Carbocation Structures as a Function of the Correlation Level in ab Initio Calculations: The 4-Methyl-2-pentyl CationThe Journal of Physical Chemistry A, 2002
- STUDIES OF POLYMER SURFACES BY SUM FREQUENCY GENERATION VIBRATIONAL SPECTROSCOPYAnnual Review of Physical Chemistry, 2002
- Molecular Bonding and Interactions at Aqueous Surfaces as Probed by Vibrational Sum Frequency SpectroscopyChemical Reviews, 2002
- Vibrational spectroscopy of interfaces by infrared–visible sum frequency generationJournal of Vacuum Science & Technology A, 2001
- Surface Enrichment in Polymer Blends Involving Hydrogen BondingMacromolecules, 2001
- Polymer surface scienceThe Chemical Record, 2001
- Hydrogen bonded polymer blendsProgress in Polymer Science, 1995
- A Crested Theropod Dinosaur from AntarcticaScience, 1994