The far ultraviolet and HeI photoelectron spectra of alkyl and fluorine substituted silane derivatives

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Abstract
The HeI photoelectron and vacuum uv absorption spectra of a number of methyl, ethyl, methylfluoro, and ethylfluoro derivatives of silane are presented. The spectra can be interpreted on the basis of their similarity to those of the related methane or ethane derivatives. The lowest lying excited states are related to transitions to 4s, 4p, and 3d orbitals having mixed Rydberg–valence shell character. The spectra can be divided into two categories: methane (’’round field’’) or ethane (’’long field’’) types. Fluorine substitution influences these spectra in a characteristic way.

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