Local and long range polar order in the relaxor-ferroelectric compounds and
- 17 December 2001
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 65 (2) , 024104
- https://doi.org/10.1103/physrevb.65.024104
Abstract
Structural evolutions of PMN/PT10% and PMN are studied and compared using high-resolution x-ray and neutron diffraction. At high temperature, PMN-like diffuse scattering, associated with local disordered shifts, is evidenced by PMN/PT10%. A part of this intensity condenses at when PMN/PT10% exhibits a structural phase transition toward a long-range rhombohedral phase, whereas in PMN the polar order remains short ranged. In the ferroelectric phase of PMN/PT10% local [100] displacements of lead are evidenced, and are connected to the observation of diffuse scattering far below The local symmetry in which oxygen and Ti/Mg/Nb cations are shifted along the [111] direction, but in which the lead atoms are shifted along one of the tetragonal [100] directions is monoclinic. This short-range polar order reconstructs on average a polar rhombohedral symmetry. A global picture for the structural evolution in the PMN/PT compounds is proposed. It is based on competition between rhombohedral and tetragonal polar order, which connects the relaxation properties of PMN and the high piezoelectric response of morphotropic monoclinic PMN/PT with a high concentration of PT.
Keywords
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