Triangular and Tetrahedral Array of Silver(I) Ions by a Novel Disk-Shaped Tridentate Ligand: Dynamic Control of Coordination Equilibrium of the Silver(I) Complexes
- 15 November 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 124 (49) , 14510-14511
- https://doi.org/10.1021/ja028659n
Abstract
A disk-shaped tridentate ligand 1 arranges silver(I) ions in a two-dimensional triangular and a three-dimensional tetrahedral fashion in the metal−ligand ratios, 3:2 and 1:1, respectively. The resulting sandwich-type (Ag312) and tetrahedral (Ag414) architectures are in a dynamic equilibrium in solution.Keywords
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