Tetracarbonylallyliron cations. A synthetic route to 2-substituted butadiene complexes

Abstract
Tetracarbonylallyiron cations have been prepared by electrophilic addition to tetracarbonyltetra-methylalleneiron; deprotonations of the salts are attended by loss of CO resulting in the formation of tricarbonylbutadieneiron derivatives with 2-substituents.

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