A monomeric molybdenum thiolato-complex with a chelated η6-arene ligand. The preparation and structure of [Mo{(η6-Ph)PhC6H3S-2,6}(SC6H3Ph2-2,6)(CO)]
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 257-259
- https://doi.org/10.1039/c39850000257
Abstract
Sodium 2,6-diphenylbenzenethiolate react with [MoBr2(CO)4] to give the chelated η6-arene complex [Mo{(η6-Ph)PhC6H3S-2,6}(SC6H3Ph2-2,6)(CO)](1) in good yield, the X-ray crystal structure of which reveales a distored ‘piano-stool’ geometry.Keywords
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