Role of the aminopyridine ring in thiamin-catalyzed reactions. II. Proton NMR evidence for high barriers to amino group rotation in 4-aminopyrimidines, including thiamin, at low pH in water
- 1 July 1982
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 47 (14) , 2748-2753
- https://doi.org/10.1021/jo00135a012
Abstract
No abstract availableThis publication has 4 references indexed in Scilit:
- Restricted rotation of the amino group bonded to thiamin and to 2-(1-hydroxyethyl)thiamin and the question of intramolecular amino group catalysisThe Journal of Organic Chemistry, 1978
- N1'-Methylthiaminium diiodide. Model study on the effect of a coenzyme bound positive charge on reaction mechanisms requiring thiamin pyrophosphateJournal of the American Chemical Society, 1978
- The protonation site of vitamin B1 as determined from natural-abundance nitrogen-15 nuclear magnetic resonance spectraJournal of the American Chemical Society, 1977
- Structure and Mechanism of Action of the Active Center of Yeast Pyruvate DecarboxylaseAngewandte Chemie International Edition in English, 1967