Novel Synthesis of HEX-2-Enopyranosides
- 1 May 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 6 (2) , 313-316
- https://doi.org/10.1080/07328308708058881
Abstract
The usefulness of thioglycosides, particularly 2-thiopyridyl glycosides2 having a suitable activating group at the anomeric center for glycosylation, has been well documented. Glycosylations of 2-thiopyridyl 4,6-di–acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside (1) with aglycones to furnish the corresponding 2,3-unsaturated-∼-glycosides have been studied. The latter compounds are suitable for the preparation of 2,3-dideoxy-sugar glycosides.Keywords
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