A high nuclearity carbonyl cluster of rhenium stabilized by an interstitial carbide; synthesis and X-ray crystal structure of the anion [Re7C(CO)21]3?
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 339-340
- https://doi.org/10.1039/c39820000339
Abstract
The trianion [Re7C(CO)21]3–, isolated from the pyrolysis of [ReH2(CO)4][NEt4] in n-tetradecane, has been characterized by an X-ray crystal structural analysis of the [PPh4]+ salt, and shown to contain a monocapped octahedral arrangement of rhenium atoms with an encapsulated carbon atom.Keywords
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