Unambiguous determination of the stereochemistry of methylcopper and lithium tetranydridoaluminate-induced allene formation in the steroid series. A revision of literature data
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 84-85
- https://doi.org/10.1039/c39820000084
Abstract
The structure of the allene obtained from mestranol methane sulphinate and methlycopper has been determinde by X-ray analysis; the allene turns out to be the 21α-Me compound, and not the erroneously reported 21β-Me epimer.Keywords
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