Asymmetric synthesis of a rigid diphosphine ligand containing two phosphorus and four carbon stereogenic centres by means of a chiral palladium complex promoted Diels–Alder reaction
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 8,p. 751-752
- https://doi.org/10.1039/a700314e
Abstract
An optically pure diphosphine ligand containing two phosphorus and four carbon stereogenic centres is prepared efficiently by a chiral organopalladium complex promoted asymmetric Diels–Alder reaction between phenyldi[(Z)-prop-1-enyl]phosphine and 1-phenyl-3,4-dimethylphosphole.Keywords
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